Alvin is attempting to win his consecutive title of "Heartthrob of the Year" award. When Alvin is in Simon's lab, he breaks a hair growth formula test tube and attempts to quickly recreate it. Instead of having it grow Simon's hair, it turns him into a heartthrob. Simon likes being Mr. Heartthrob so he tries to drink more. Alvin stops him, taking the heartthrob formula, leaving Simon to believe his hair growth formula is responsible so he makes a vial. Theodore steals the vial from Simon, giving it to Alvin while Simon finds the hearttrob formula in Alvin's spare hat. When they perform, Simon becomes Mr. Hearttrob while Alvin grows hair everywhere. After the performance, Alvin loses "Heartthrob of the Year" award, but not to Simon, who suddenly reverts back to his old self and loses because he was not himself. The winner is Theodore! Simon thinks he is a failure as a chemist but is proven wrong when Dave drinks the real hair growth formula.
- "Yesterday And You" originally performed by David Seville (Ross Basgadrian, Sr).